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I think he missed a 100 % opportunity in the beginning of the match and for me that was the decisive moment. It was clear as sky that Real needed an early goal and he missed a chance in the 4th minute. I also think that his stats in the CL were something like 8 goals in 50 matches, even Quagliarella has a better ratio .
I know it's ridiculous, but what the hell, let's recall what happened versus Dortmund:
1st Leg:
Pepe loses Lewandowski and he scores 1-0
Higuain capitalize on Hummels mistake and provide Ronaldo with a goal 1-1
Pepe keeps Lewandowski onside for the goal 2-1
Pepe get kept watching Lewandowski scoring from inside the area 3-1
Alonso fouls Rues for a penalty, Lewandowski scores 4-1
2nd Leg:
Higuain misses a clear chance 0-0
Ozil misses an incredible 1-on-1 with the GK 0-0
Ronaldo misses by shooting straight at the GK 0-0
Ronaldo misses again with a shot 0-0
Di Maria misses with a long shot 0-0
Benzema scores too late 1-0
Ramos scores at stoppages 2-0
Are you sure Higuain is the reason Real were knocked out by Dortmund? If you want to ignore Pepe's first leg heroics and the fact that Higuain is the reason Real scored an away goal, then just look at the chance Ozil missed compared to the one Higuain missed. Ronaldo was also miserable in the 2nd leg.