Caceres is not a proper CB in a 3-5-2 or a 4-3-3. He's the one who lost Gomez, it's clear as day. Someone like Barzagli maybe can read that play better but there are few CBs who would have done much different than Ogbonna. Caceres has to either step up to Ogbonna and put Gomez offside or keep running with him. He just lets him go.
Ogbonna got caught on one turn by Valero but it ended up in a foul. He shanked one ball to the keeper after being put under pressure by Chiellini. Other than that he had a superb ball to Isla to start an attack and a superb ball to Vidal under pressure near his own corner flag to start another attack. I can't think of many other misplaced passes TBH, perhaps there were a couple others, certainly nothing like a Bonucci error to start a counter attack. A couple times Fiorentina took all his options away and he pushed on with the ball a bit too much but ultimately found a teammate even though it was clumsy at times.
He pressured a Matri chance into a miss, he had a bike clearance in the 6 yard box (Asamoah had one too). Blocked a hard shot with his head (didn't deflect it into his net like Bonucci lol), won every aerial ball vs. Matri. Won several balls with his head in his own box.